Those of you looking at deploying Outlook 2010 on your systems will need to be aware that outlook captured on XP will not run on Win7 or visa-versa.
The reason is that Outlook 2010 has a fundamentally different install for XP and Win7, so if you need to support both OSs you'll have to capture Outlook 2010 twice--once for XP and once for Win7. Note: You can still capture 32-bit outlook on either Win7 versions and it will run when you move it to a different architecture.
Another note is PST and OST corruption with Outlook 2007, though it's recommended to do the following for Office 2010. You'll need to add the following Exclude entries to the layer [APPDATA] w/subdir and [LOCALAPPDATA] w/subdir. Keen eyed users will realized that this will prevent reset from really working as intended, because all the user data will be excluded from the layer, so those of you that want to avoid that reset issue can exclude the following file types from your layer: .OST, .PST, .TMP
However, the directory method is the official supported solution.