Sour1,
I am not sure if this is possible for DLP does not break down the fields in the Email Headers, when it comes to policies.
Though you might be able to look for a keyword of "BCC" and ONLY look in the "Header". You may need to figure out how it tags the BCC people, so it may not be BCC to look for.
I would assume that the header BCC does not exist if it is empty. So by lookng for BCC in the header might mean it exists.
I am not sure if we see the BCC or if we process it as a tag.
Just a thought
Good Luck
Ronak
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