Hey Nitass,
So I can understand this is a little confusing. Recipient Validation is actually an option available "instead of" synchronization. Recipient Validation does a lookup at the time of validating the recipient instead of keeping a synchronized database of entries to querry. And actually may be a better option for you depending on your needs.
To answer your second question, you can use either synchronization or recipient validation for dropping of invalid recipients.
And lastly, we will keep a listing of entries in either case to continue to have a proper listing of users. So in the worst case, you could just turn off dropping of invalid recipients if your LDAP server goes down. But I don't believe it will drop all mail.
Hope this helps!
Tom