Greetings,
That is very odd behavior for scan engine. We do see unscannables for container violations and typically not for malformed container for MS created documents.
I suspect that you may be having issues with compressed files such as .zips. The 2007-2010 office documents with the x extension are just zip files.
I would recommend to make sure that definitions have been updated. I have seen with other Symantec products where the product can load definitions, but some of the data is corrupt causing oddities in scanning for different file types.
Please review the following document for repairing definitions.
How to apply Intelligent Updater virus definitions manually to Symantec Scan Engine 5.x
http://www.symantec.com/business/support/index?page=content&id=TECH90925