I suspect this can be done in a PGP Universal setting when keys are managed at that level.
Let me clarify how NetShare works, at least for PGP Dekstop users. When files are placed in a NetShare protected folder by a PGP NetShare authorized user of that folder, the files are encrypted to the public keys of all authorized users of that protected folder. When this folder is on a server, and a file it contains is accessed by an authorized user of that protected folder, the file is sent over the network in an encrypted state to the authorized user. After it reaches the user's computer, the user's private key then transparently decrypts the file for use. However, since the user's private key is encrypted to the user's passphrase, the passphrase is necessary for the decryption of the private key, so that it can then decrypt the file - unless the passphrase has been cached, it must then be entered.
What you might want to try (I'm not sure if it will work), taking into account that this is not recommended due to the lowered security of the protected files if you do, is to change a user's key's passphrase, and not make any entry for the new passphrase - since this results in having no passphrase for the encryption of the private key, that private key will no longer be encrypted.