Will PCAnywhere12.5 work with Windows8.1 64bit operating system
not yet, see here
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Currently Pcanywhere not supported windows 8/8.1
You can pprovide your input here
12.5 is not supported for window8 but check the Jagaman comment and try the same may be it can resolve your issue.
What is the pcAnywhere "Mirror Driver"?
Article:TECH110005 | Created: 2008-01-08 | Updated: 2013-07-05 | Article URL http://www.symantec.com/docs/TECH110005