Hello Hemu,
The SMB (Server Message Block) protocol is used among other things for file sharing in Windows NT/2000/XP. In Windows NT it ran on top of NetBT (NetBIOS over TCP/IP), which used the famous ports 137, 138 (UDP) and 139 (TCP). In Windows 2000/XP/2003, Microsoft added the possibility to run SMB directly over TCP/IP, without the extra layer of NetBT. For this they use TCP port 445.
This is owned by microsoft and there is now way you can change it...
Hope this answers your question.