It's not a matter of whether Prevent supports Postfix in either reflection or fowarding mode...it's a matter of Postfix supporting mail routing in such a way that allows one to put Prevent in reflection mode. Some fully SMTP compliant MTA's don't necessarily allow for routing email in such a way that would support reflection.
Symantec's documentation on this is rather ambiguous (or it was the last time I read it, though it may have been updated). It describes the forwarding and reflection modes, and states that SMTP Prevent can integrate with fully SMTP compliant MTA's. But what it doesn't say is that not all MTA's can support the routing of mail in such a way as to support reflection (whether your using IP, port, or header-based routing rules).
~Keith