Easiest way to check:
Open Workflow Explorer. Go to the SymQ Configuration tab. Check the local.workflow- queue (2nd from the bottom) and see what this alias exchange is delivering to.
If its local.workflowsqlexchange-, it's SQL based. If it's file based, it'll be delivering to some file exchange (can't think of the name off the top of my head - LocalFileStorage-, I think).
Note that workflow persistence is server-based, not on a per workflow basis. If your workflow server persistence is SQL based, all of them use SQL to persist their data.
Also, it's advised not to change these exchanges unless you know what you're doing. Flipping from SQL to file persistence will likely result in lost data unless you take precautions.